CDMRR - P DICHLOROBENZENE
- MSDS: CDMRR
- Manufacturer: FISHER SCIENTIFIC
- Product Name: P DICHLOROBENZENE
- National Stock Number: 6810-00N046185
Product Identification
Product ID:P DICHLOROBENZENE
MSDS Date:03/24/1993
FSC:6810
NIIN:00N046185
MSDS Number: CDMRR
Responsible Party
FAIR LAWN, NJ 07410
US
Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)
Info Phone: 201-796-7100
Cage: 1B464
Contractor
Telephone: 201-796-7100
Cage: 1B464
Ingredients
ADENOMAS & PHEOCHROMOCYTOMAS OF ADRENAL GLAND IN
RTECS: 9999999ZZ
MONONUCLEAR CELL LEUKEMIA REPORTED IN RATS. REPRO
RTECS: 9999999ZZ
UNTIL NO EVID OF CHEM REMAINS, AT LST 15-20
RTECS: 9999999ZZ
LAVAGE/EMESIS. MAINTAIN BLOOD PRESS & AIRWAY. DO NOT
RTECS: 9999999ZZ
STIMULANTS WHICH MAY INDUCE VENTRICULAR
RTECS: 9999999ZZ
NO
RTECS: 9999999ZZ
ISOLATE HAZARD AREA & DENY ENTRY. VENTILATE
RTECS: 9999999ZZ
CONCERNING OTHER TYPES OF SPILLS, CONTACT NEHC .
RTECS: 9999999ZZ
BENZENE, P-DICHLORO-; (P DICHLOROBENZENE) (SARA 313)
CAS: 106-46-7
RTECS: CZ4550000
Fraction By Weight: 99%
OSHA PEL 75 PPM
ACGIH TLV: 10 PPM
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
BENZENE, M-DICHLORO-; (M-ISOMERS)
CAS: 541-73-1
RTECS: CZ4499000
Fraction By Weight: <0.08%
OSHA PEL N/K
ACGIH TLV: N/K
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
BENZENE, O-DICHLORO-; (O-ISOMERS)
CAS: 95-50-1
RTECS: CZ4500000
Fraction By Weight: 0.08%
OSHA PEL N/K
ACGIH TLV: N/K
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
PARTICLES MAY CAUSE REDNESS & PAIN BUT NO SERIOUS
RTECS: 9999999ZZ
ABDOM PAIN, VOMIT, DIARR, COUGH,
RTECS: 9999999ZZ
IN ADDN TO ACUTE INHAL
RTECS: 9999999ZZ
LEUKEMIA, GRANULOMASTOSIS, HYPOGRANULOCYTOSIS,
RTECS: 9999999ZZ
W/JAUN, OLIGURIA, CIRRHOSIS & DEATH. NYSTAGMUS,
RTECS: 9999999ZZ
RPTD/PRLNGD CNTCT W/WARM
RTECS: 9999999ZZ
RABBITS DEVELOPED TRANSIENT EDEMA OF CORNEA/OTHER
RTECS: 9999999ZZ
ANIMALS, CHRONIC FEEDING RSLTD IN WT LOSS, TREMORS,
RTECS: 9999999ZZ
FOCAL NECROSIS IN LIVER & NONNEOPLASTIC LESIONS OF
RTECS: 9999999ZZ
OF 1000MG/KG WHEN 92 DOSES GIVEN IN 219 DAYS. 2 YR
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:IRRITANT/HEPATOTOXIN.
1000PPM IMMED DANGEROUS TO LIFE/HLTH. MUC MEMB IRRIT. SEV HDCH,
DYSPNEA, ASTHENIA, NUMB, BURNING SENSATION IN LEGS, COUGH,
RESTLESSNESS, FAINTNESS, TREMORS, LOSS OF APPETITE, NAUS, VOMIT,
WT LOSS, VERTIGO, PERIORBITAL SWELL, PROFUSE RHINITIS, CNS
STIMULATION FOLLOWED(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE, P-DICHLORO:IARC MONOGRAPHS,
SUPP, VOL 7, PG 192, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS,
1994: (SUPDAT)
Effects of Overexposure:HLTH HAZ:BY DEPRESS. SWELL OF HANDS, FEET &
ANKLES. ACUTE GLOMERULAR NEPHRITIS & LIVER DMG W/YELLOW JAUN & POSS
DEATH. IF DEATH DOES NOT OCCUR CIRRHOSIS MAY BE PRDCED. SYMPS
SUBSIDED W/IN 24 HRS AFTER CESSATION OF EXPOS. SKIN:CNTCT
W/SOLIDCAUSES SLIGHT IRRIT, ALTHOUGH PRLNGD CNTCT MAY CAUSE BURNING
SENSATION. (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
First Aid
First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED,
PERFORM ARTF RESP. KEEP PERSON WARM & AT REST. TREAT SYMP &
SUPPORTIVELY. GET MED ATTN IMMED. SKIN:REMOVE CONTAMD CLTHG & SHOES
IMMED. WASH AFFEC TED AREA W/SOAP OR MILD DETERGENT & LG AMTS OF
WATER UNTIL NO EVID OF CHEM REMAINS, APPROX 15-20 MIN. GET MED ATTN
IMMED. EYE:WASH IMMED W/LG AMTS OF WATER/NORM SALINE OCCASNLY
LIFTING LIDS (ING 16)
Fire Fighting
Flash Point Method:CC
Flash Point:150F,66C
Lower Limits:2.5%
Upper Limits:9.6%
Extinguishing Media:DRY CHEM, CARBON DIOXIDE, WATER SPRAY OR REGULAR
FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM FIRE AREA IF W/OUT RISK. APPLY COOLING WATER TO SIDES OF
CNTNRS EXPOS TO FLAMES UNTIL WELL (SUPDAT)
Unusual Fire/Explosion Hazard:MODERATE FIRE HAZARD WHEN EXPOSED TO HEAT
OR FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
Accidental Release
Spill Release Procedures:DO NOT TOUCH SPILLED MATL. STOP LEAK IF YOU
CAN DO IT W/OUT RISK. FOR SM SPILLS, TAKE UP W/SAND OR OTHER ABSORB
MATL & PLACE INTO CNTNRS FOR LATER DISP. FOR LARGER SPILLS, DIKE
FAR AHEAD OF SPILL FOR LATER DISP. KEEP UNNEC PEOPLE AWAY. (ING
20)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:OBSERVE ALL FEDERAL, STATE AND LOCAL
REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE.
Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY.
Exposure Controls
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . FOR A COMPLETE LISTING OF RECOMMENDED
RESPIRATORS CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION
SYSTEM.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT RPTD/PRLNGD SKIN
CNTCT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:ANTIC TO BE CARCIN. ANIMAL:KIDNEY, BLADDER, URETER,
LIVER. EFTS OF OVEREXP:ONE CASE OF ALLERGIC PURPURA REPORTED. NO
EVID OF SIGNIFICANT ABSORPTION THRU SKIN, HOWEVER DERMAL EXPOS COU
LD CONTRIBUTE TO OVERALL TOX OF CHEM IFSUFFICIENT AMTS ARE
ABSORBED. EFTS MAY OCCUR AS W/INHAL. EYES: SOLID (ING 4)
Chemical Properties
Boiling Pt:B.P. Text:345F,174C
Melt/Freeze Pt:M.P/F.P Text:127F,53C
Vapor Pres:0.4 @ 20C
Vapor Density:5.1
Spec Gravity:1.46
Solubility in Water:0.008%
Appearance and Odor:COLORLESS OR WHITE CRYSTALS WITH AN ODOR LIKE
MOTHBALLS.
Stability
Stability Indicator/Materials to Avoid:YES
ALAKLI METALS, METAL PWDRS:VIOLENT RXN. OXIDIZERS (STRONG):FIRE & EXPLO
HAZ. PLASTICS, RUB & COATINGS MAY BE ATTACKED.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODS MAY
INCLUDE HIGHLY TOX FUMES OF PHOSGENE, TOX & CORR FUMES OF CHLORIDES
& OXIDES OF CARBON.
Disposal
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE. DISPOSAL MUST BE IN
ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS
WASTE, 40 CFR 262. EPA HAZARDOUS WASTE NUMBER U072. RQ - 100 LBS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.